Crude oil

Section 1 of 4

Petrol, diesel, jet fuel, bottled gas and the black surface of many roads all start as one thick, dark liquid pumped up from deep underground: crude oil.

Crude oil is a mixture of thousands of different hydrocarbons, the compounds of only carbon and hydrogen that you have met many times. Some are chains, the alkanes. Many are rings of carbon atoms, such as cyclohexane, and some carry the flat benzene ring. Their sizes run from methane, with one carbon, to big molecules with dozens.

Hexane, C₆H₁₄Six carbon atoms in a straight chain, joined by single bonds, with fourteen hydrogen atoms around them.
Hexane, C₆H₁₄: a chain
Cyclohexane, C₆H₁₂Six carbon atoms joined by single bonds in a ring, each carbon also bonded to two hydrogen atoms.
Cyclohexane, C₆H₁₂: a ring
Benzene, C₆H₆Six carbon atoms in a flat ring, drawn with alternating single and double bonds, each carbon also bonded to one hydrogen atom.
Benzene, C₆H₆: a benzene ring

Made from tiny sea life

Crude oil formed over millions of years from plankton: tiny algae and animals that drifted in ancient seas. When they died, they sank and were buried in mud on the sea floor, where there was too little oxygen for them to rot away. More mud and sand piled on top and slowly turned to rock. Deep underground, heat and pressure turned their remains into crude oil and natural gas.

Oil and gas are lighter than water, so they creep upwards through porous rock, rock such as sandstone with tiny spaces between its grains. Where they meet a layer of cap rock, rock with no spaces between its grains such as shale, they collect beneath it. Oil companies drill down through the cap rock to reach them.

Crude oil and natural gas trapped under a dome of rock A slice through the ground under the sea. Layers of rock bend up into a dome. At the bottom, a layer holds the remains of plankton, buried long ago. Above it, a layer of porous rock holds crude oil, with a pocket of natural gas above the oil at the top of the dome. A layer of cap rock above them, with no spaces between its grains, stops the oil and gas rising any further. sea cap rock natural gas crude oil porous rock plankton remains
Oil and gas rise through porous rock and collect under a dome of cap rock. The gas is lighter, so it sits above the oil.

Straight from the ground, crude oil has few uses. A refinery sorts it into useful parts, and the next section shows how.

Quick check

Crude oil is a mixture. What does that tell you about it?