Lesson 1: Meet carbon

Same atom, different stuff

Section 3 of 4

Diamond is the hardest natural material on Earth. The "lead" in a pencil is soft enough to rub off on paper. Both are made of nothing but carbon atoms. So how can they be so different?

The answer is in how the atoms are joined.

Diamond: a 3D network of carbon A small piece of diamond drawn in 3D, with nearer atoms drawn larger. Every carbon atom inside the network is bonded to 4 others, spread out in 3D. One atom in the middle is highlighted with its 4 bonds. The atoms join in rings of six.
Diamond, a small piece drawn in 3D: nearer atoms are drawn bigger. Every carbon atom inside is bonded to 4 others, and the atoms join in rings of six.
Graphite: stacked sheets of carbon Two flat sheets of carbon atoms drawn in 3D, one stacked above the other like pages. In each sheet the atoms join in hexagons, and each atom inside a sheet is bonded to 3 neighbours. One atom in the top sheet is highlighted with its 3 bonds. There are no bonds between the sheets.
Graphite, two small pieces of its sheets drawn in 3D. Inside a sheet each carbon atom is bonded to 3 others in hexagons. The gap between the sheets is drawn wider than it really is.

In diamond, every carbon atom uses all four hands to grip four other carbon atoms. The bonds point in every direction, so the whole crystal is one giant, rigid network. To scratch it you would have to break a huge number of bonds. That is why diamond is so hard.

In graphite, each carbon atom bonds to only 3 neighbours, in flat sheets of hexagons. Its fourth outer electron is shared across the whole sheet, which is why graphite conducts electricity. The sheets are stacked like pages, held together by a weak pull, so they slide over each other easily. When you write with a pencil, sheets of graphite slide off onto the paper.

Quick check

Diamond and graphite are both pure carbon. Why is diamond hard but graphite slippery?